Start by soaking the ancho chilies for the mole sauce. Place the chilies in a small bowl and cover with boiling water. Allow to soak for 10-15 minutes, then drain the water and remove the stalks from the chilies when cool enough to touch.
To make the sauce, place the soaked chilies together with all of the other mole sauce ingredients into a blender or food processor, and blend together until smooth and evenly combined. Set aside.
Prep the rest of the ingredients. Crush or finely chop the garlic. Cut open the chili, scrape out and discard most seeds, and finely chop the skin. Slice up the onion and capsicum. Cut the chicken thighs into large chunks.
Once the pan is hot add the chicken, onion and garlic. Cook for a few minutes, turning a little, until the chicken is turning white all over. Throw in the capsicum and chili and continue to cook for 2-3 minutes, until everything is slightly softened and the chicken is browning
Pour in the mole sauce. Stir it in until everything is evenly distributed in the pan. Allow the sauce to reach a rapidly bubbling simmer, then reduce the heat to low, so it gently bubbles away.
Cook the chicken for at least 20 minutes, uncovered so the sauce thickens, stirring occasionally. If you have time, you can reduce the heat to super low and simmer this, partially covered, on the stove for anywhere from 1 to 2 hours, until the thigh meat is really soft and can be shredded through the sauce. A little extra water can be added during the cooking process to keep the sauce to your desired consistency.
While the mixture is simmering away, make any sides that you'd like to serve with the chicken. Once done, plate it all up and serve hot.
Notes
*I use a common large red chilli that you typically find in supermarkets. This ingredient is just to add additional heat to the mole, and you can adjust the amount you use to suit your personal preference. Also, I know there are a huge variety of chillies available; if you pick up one of the smaller, hotter chillies, you can adjust the amount to account for that, too!*If you want a darker, richer sauce, add an extra tablespoon or two of cacao powder.*If you prefer not to use stevia, this can be substituted for an equivalent amount of honey or maple syrup.
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